The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / C2H5O2 / Munk(1986)_298K_200-300nm(2nm,orig)

DATAFILE: C2H5O2_Munk(1986)_298K_200-300nm(2nm,orig).txt
NAME: ethylperoxy radical
FORMULA: C2H5O2
AUTHOR(YEAR): Munk(1986)
T: 298K
λ: 200-300nm(2nm,orig)
BIBLIOGRAPHY: J. Munk, P. Pagsberg, E. Ratajczak, and A. Sillesen, "Spectrokinetic studies of ethyl and ethylperoxy radicals", J. Phys. Chem. 90, 2752-2757 (1986); DOI: 10.1021/j100403a038
COMMENTS: Absorption measurements following pulse radiolysis of H2/C2H4/O2 mixtures; spectrum scaled to σ(HO2) = 4.5×10-18 cm2 molecule-1 at 210 nm

Extinction coefficients plotted in Fig. 1 have been digitized, converted to absorption cross sections (conversion factor 3.8235×10-21), and then interpolated at 10-nm intervals

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